Part No: RXSOL-19-1227-210
Ammonium Hydroxide Solution Liquid Ammonia 25%
Category
Safety Data (MSDS)
| Porduct Name | Ammonia Aqueous |
| Part Number | RXSOL-60-6608-010 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
| Chemical Name | Cas No | EC No | Whight | Formula |
| Ammonia solution 25% for analysis EMSURE® ISO,Reag. Ph Eur | 1336-21-6 | 215-647-6 | >= 25 - 30 % | NH4OH |
| Signal Word | Danger |
| Hazard Statements | H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. |
| Precautionary statements | P261 Avoid breathing mist or vapors. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Supplemental Hazard Statements | None |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | First aiders need to protect themselves. |
| If inhaled | After inhalation fresh air. Call in physician |
| Eye Contact | After eye contact rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| Swallowed | After swallowing make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
| Skin Contact | In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Nitrogen oxides (NOx) Not combustible. Ammonia solution itself is not flammable, but can form an ignitable ammonia/air-mixture by outgassing. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: nitrogen oxides |
| Further information | Cool closed containers exposed to fire with water spray. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
| Advice on protection against fire and explosion | No data available |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Advice on safe handling | Observe label precautions |
| Conditions for safe storage, including any incompatibilities | No data available |
| Storage conditions | No metal or light-weight-metal containers. Tightly closed. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 8B Non-combustible, corrosive hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Eye/face protection | Tightly fitting safety goggles |
| Exposure control | Personal protective equipment |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact |
| Body Protection | Protective clothing |
| Respiratory protection | Recommended Filter type Filter type K The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Stinging |
| Odor Threshold | Not Applicable |
| pH | at 20 °C strongly alkaline |
| Melting Point | -57,5 °C |
| Boiling Point | 37,7 °C at 1.013 hPa |
| Flash Point | 6 °C - closed cup |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | Upper explosion limit33,6 %(V) Lower explosion limit 15,4 %(V) |
| Autoignition temperature | No data available |
| Decomposition temperature |
No data available |
| Vapour pressure | 483 hPa at 20 °C |
| Viscosity | No data available |
| Density | 0,903 g/cm3 at 20 °C |
| Relative Density | No data available |
| Specific Gravity | No data available |
| Partition coefficient | Log Pow -1,38 - (anhydrous substance), (Lit.), Bioaccumulation is not expected. |
| Explosive properties | No data available |
| Solubility | at 20 °C soluble |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | No data available |
| Chemical stability | Ammonia solution itself is not flammable, but can form an ignitable ammonia/air-mixture by outgassing. |
| Possibility of hazardous reactions | Oxidizing agents Mercury Oxygen silver compounds nitrogen trichloride hydrogen peroxide silver antimony hydride Halogens Acids Calcium Chlorine Chlorites auric salts perchlorates sodium hypochlorite mercury compounds halogen oxides Heavy metals Heavy metal salts Acid chlorides Acid anhydrides Risk of ignition or formation of inflammable gases or vapours with: Boranes Millipore- 1.05432 Page 8 of 14 The life science business of Merck operates as MilliporeSigma in the US and Canada Boron Oxides of phosphorus Nitric acid silicon compounds chromium(VI) oxide chromyl chloride Exothermic reaction with: Acetaldehyde Acrolein Barium boron compounds Bromine halogen-halogen compounds hydrogen bromide silane Hydrogen chloride gas halogen compounds dimethylsulfate nitrogen oxides Fluorine Hydrogen fluoride chlorates carbon dioxide Ethylene oxide polymerisable |
| Conditions to avoid | Heating |
| Incompatible materials |
Aluminum, Lead, Nickel, silver, Zinc, Copper, metal alloys, various metals
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | mucosal irritations, Cough, Shortness of breath, bronchitis, Possible damages:, damage of respiratory tract |
| Skin corrosion/irritation | Rabbit Severe irritations (29% solution) (RTECS) Dermatitis Necrosis |
| Serious eye damage/irritation | Eyes - Rabbit Severe irritations (29% solution) (RTECS) Mixture causes serious eye damage. Risk of blindness! |
| Respiratory or skin sensitization | No data available |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | No data available |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure |
No data available
|
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Cough Shortness of breath bronchitis gastric pain Bloody vomiting Nausea collapse shock Unconsciousness Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. |
| Persistence and degradability | No data available |
| Toxicity to fish | Flow-through test LC50 - Pimephales promelas (fathead minnow) - 0,068 mg/l - 96 h (ECHA) The value is given in analogy to the following substance: ammonium sulphate |
| Toxicity to daphnia and other aquatic invertebrates | Static test LC50 - Daphnia magna (Water flea) - 101 mg/l - 48 h (ECHA) anhydrous |
| Toxicity | No data available |
| Toxicity to bacteria | No data available |
| Toxicity to algae | No data available |
| Products Biodegradation | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Biological effects Harmful effect due to pH shift. Forms toxic and corrosive mixtures with water even if diluted. Discharge into the environment must be avoided. No data available |
| Product | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID:2672 IMDG:2672 IATA:2672 |
| UN proper shipping name | ADR/RID:AMMONIA SOLUTION IMDG:AMMONIA SOLUTION IATA:AMMONIA SOLUTION |
| Transport hazard class(es) | ADR/RID:8 IMDG:8 IATA:8 |
| Packaging group | ADR/RID:lll IMDG:lll IATA:lll |
| Environmental hazards | ADR/RID:Yes IMDG:Yes IATA: No |
| Special precautions for user | Tunnel restriction code (E) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | No data available |
| Chemical Safety Assessment | For this product a chemical safety assessment has been carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |